In this paper, the Pb(1-a-b)BaaSrb(ZrxTiy)1-c-d(Bi3/2W1/2)c(Sb1/2Nb3/2)dO3 quaternary piezoelectric ceramic materials were prepared by the solid phase reaction method. Through the proportion of the each component adjustment and appropriate doping modification, the transverse piezoelectric strain constant (d31) of -490 pm/V, dielectric constant of 4 500 and dielectric loss of less than 2% have been realized in the material.By adopting the dry pressing, cold isostatic pressing (CIP) and optimizing the sintering process, the largesize piezoelectric ceramic bulk with the theoretical density of above 99% and the size of 170 mm×15 mm has been prepared. The work lays the foundation for the development of glassbased piezoelectric ceramic films for largediameter deformable mirror.