基于薄层铱配合物的有机电致发光器件研究
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国家自然基金创新群体基金资助项目(61021061);国家自然科学基金资助项目(61177032);教育部博士点基金资助项目(20090185110020);教育部留学归国基金资助项目(GGRYJJ08 05);中央高校基本科研业务费专项经费基金资助项目(ZYGX2010Z004, ZYGX2009J054, ZYGX2010J004)

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Study on White Organic Light emitting Devices Based on Dual iridium Complex Ultrathin Layers
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    摘要:

    采用蓝色磷光染料 bis[(4,6 diflourophenyl) pyridinato N,C2’)](picolinato) Iridium(III)(FIrpic)和黄色磷光染料 bis[2(4tertbutylphenyl)benzothiazolato N,C2,] iridium(acetylacetonate) [(t-bt)-2Ir(acac)]为超薄层,制备了结构为 ITO/NPB/mCP/(t bt)2Ir(acac)/mCP/FIrpic/mCP/TPBi/Mg∶Ag的白色有机电致发光器件。通过调节磷光染料双超薄层FIrpic和(t-bt)-2Ir(acac)的厚度,优化了白光器件的性能。结果表明,白光器件的最高电流效率为13.08 cd/A,最高功率效率为7.21 lm/W,发光光谱稳定,在9 V时得到色坐标为(0.33,0.33)的标准白光,并且在较宽的电压范围内仅有(±0.08,±0.08)变化。这是由于超薄层FIrpic和(t-bt)-2Ir(acac)形成的陷阱效应直接俘获电子和空穴,从而将载流子复合区域限制在一定范围内,不仅有利于增加激子的辐射发光效率,且提高了光谱的稳定性。

    Abstract:

    The white organic light emitting devices (OLEDs) with a structure of ITO/NPB/mCP/(t-bt)2Ir(acac)/mCP/FIrpic/mCP/TPBi/Mg∶Ag were fabricated using a blue and yellow phosphorescent dyes of bis[(4,6 diflourophenyl) pyridinato N,C2’)](picolinato) Iridium(III) (FIrpic) and bis[2-(4-tertbutylphenyl)benzothiazolato N,C2,]iridium (acetylacetonate)[(t bt)2Ir(acac)] as ultrathin layers, respectively.The performance of white OLEDs has been optimized by adjusting the film thickness of (t bt)2Ir(acac) and Firpic.The results showed that a pure white organic light emission was obtained with a current efficiency of 13.08 cd/A and a power efficiency of 7.21 lm/W.The CIE (Commissions Internationale De L’Eclairage) coordinates near (0.33,0.33) was observed at 9 V with a slight variation of (±0.08,±0.08) in a wide range of voltages.The high power efficiency and stable electroluminescence were attributed to the confining emission zone function of direct carrier trapping in the ultrathin layers.

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曾国庆,林慧,张磊,张伟,于军胜.基于薄层铱配合物的有机电致发光器件研究[J].压电与声光,2013,35(2):250-254. ZENG Guoqing, LIN Hui, ZHANG Lei, ZHANG Wei, YU Junsheng. Study on White Organic Light emitting Devices Based on Dual iridium Complex Ultrathin Layers[J]. PIEZOELECTRICS AND ACOUSTOOPTICS

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  • 在线发布日期: 2013-04-08
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