YMnO3掺杂对BCZT无铅压电陶瓷性能的影响
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国家自然科学基金青年基金资助项目(51107077)

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Effects of YMnO3 Doping on Properties of BCZT Lead free Piezoelectric Ceramics
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    摘要:

    采用传统固相法成功制备了(1-x)(Ba0.85Ca0.15)( Zr0.05Ti0.95)O3 -xYMnO3(BCZT-YMn)无铅压电陶瓷,研究了YMnO3掺杂对BCZT陶瓷相结构及电性能的影响。结果表明,陶瓷在相变中出现了铁电性优化的现象,当x=0.060时,获得了较佳的铁电性能,外加电场强度为4 kV/mm时,其剩余极化强度为18.03 μC /cm2,矫顽电场强度为0.9 kV/mm,室温下介电常数为3 375,最大介电常数为3 507。当x>0.060时,铁电性突变消失,介电性出现居里峰展宽的现象,同时居里温度亦随之变化。

    Abstract:

    (1-x)(Ba0.85Ca0.15)( Zr0.05Ti0.95)O3-xYMnO3(BCZT YMn) lead free ceramics were prepared by the traditional solid state reaction method. The effect of YMnO3 doping on the phase structure and dielectric properties of the ceramics was studies. The results showed that the ferroelectric properties were improved during phase transition. The optimum ferroelectric properties (the remanent polarization was 18.03 μC/cm2 , the coercive field was 0.9 kV/mm, the room dielectric constant was 3 375, the maximum dielectric constant m was 3 507) were obtained at x=0.060 while the electric field intensity was 4 kV/mm. The ferroelectricity mutations disappeared and the curie peak was broaden at x>0.060. At the same time, the curie temperature was shifted.

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贺立龙,张永战,晁小练,杨祖培. YMnO3掺杂对BCZT无铅压电陶瓷性能的影响[J].压电与声光,2014,36(5):772-774. HE Lilong, ZHANG Yongzhan, CHAO Xiaolian, YANG Zupei. Effects of YMnO3 Doping on Properties of BCZT Lead free Piezoelectric Ceramics[J]. PIEZOELECTRICS AND ACOUSTOOPTICS

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  • 在线发布日期: 2014-09-25
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