CaO-ZnO-B2O3低温烧结LiZn铁氧体旋磁性能研究
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国家自然科学基金资助项目(No. 61021061,51272036,51002021,61131005);国际合作基金资助项目(No. 2012DFR 10730,2013HH0003)

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Study on Modification of the Low temperature Co firing Characteristic for LiZn Ferrites with CaO-ZnO-B2O3 Glass Addition
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    摘要:

    用固相法制备Li0.45Zn0.3Ti0.2Mn0.03Mn0.03Fe1.99O4铁氧体,研究了CaO-ZnO-B2O3(CZB)玻璃助烧剂对磁性能和结构的影响。结果表明,适量的CZB玻璃相可促进固相反应,显著降低烧结温度。通过X线衍射(XRD)和扫描电镜 (SEM)分析表明,CZB玻璃没有影响LiZn铁氧体的尖晶石相结构,且其可促进晶粒生长。磁性能变化规律表明,CZB的质量分数为0.25%时,饱和磁感应强度(Bs)达最大,矫顽力(Hc)降低。Hc在质量分数为2.5%时达到最小,随后有所上升。微掺杂时,毛细管力起主导作用,少量掺杂时,液相中的扩散起主导作用,两者都促进了固相反应。过量掺杂时,玻璃相阻碍晶粒生长,各项异性场增大,导致Bs下降、Hc和铁磁共振线宽(△H)增大。添加CZB的LiZn铁氧体在910 ℃时具有较好的磁性能,可兼容低温共烧技术应用于移相器的设计。

    Abstract:

    The influences of CZB(CaO-ZnO-B2O3 ) (CZB) glass addition on magnetic properties and structures of ferrite (Li0.45Zn0.3Ti0.2Mn0.03Mn0.03Fe1.99O4) prepared by the standard solid state reaction method was investigated.The results show that the sintering temperature of ferrites was reduced due to the induction of appropriate amount of CZB.X Ray Diffraction(XRD) and Scanning electron microscopy(SEM) analysis reveals that the glass phase doping has no effect on the structure of LiZn ferrite.Meanwhile,the grain size achieves a significant growth. The magnetic curve shows that the CZB can not only exhibit the maximal Bs at 0.25% but also low Hc values distinctly.With the increasing of CZB glass,the coercivity (Hc) decreases,reaching a minimum at 2.5% and then increases slightly.The solid phase reaction was promoted due to the key roles of the capillary pressure with few CZB glass addition.Doping small CZB glass,the solid phase reaction was also promoted.This could be attributed to a dominant diffusion effect in liquid.When the glass was added to excess,glass phase will obstruct the grain in growth so that anisotropy field was increased at the same time,in which a increase in Hc and △H and a decrease in Bs.The LiZn ferrite with CZB glass addition obtains well magnetic properties at sintering temperature of 910 ℃.As a result,this could apply to a design for phase shifter by using LTCC technology.

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王明,杨青慧,张怀武,贾利军,廖玉龙,苏桦,周廷川. CaO-ZnO-B2O3低温烧结LiZn铁氧体旋磁性能研究[J].压电与声光,2015,37(1):88-91. WANG Ming, YANG Qinghui, ZHANG Huaiwu, JIA Lijun, LIAO Yulong, SU Hua, ZHOU Tingchuan. Study on Modification of the Low temperature Co firing Characteristic for LiZn Ferrites with CaO-ZnO-B2O3 Glass Addition[J]. PIEZOELECTRICS AND ACOUSTOOPTICS

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  • 在线发布日期: 2015-01-22
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